Sending would be possible via a so called relay server (e.g. smtp2go) which can be configured to use a different port.
However if port 25 is not open inbound to mailcow, you will never receive mails.
Sounds like you want to setup a mail server on a residential internet connection. That is a really difficult topic, because of all the limitiations like port 25 blocked, no PTR DNS record, dynamic IP address, or not having a proper public IPv4 address, as many ISPs are using CG-NAT nowadays.